Journal
ORGANIC LETTERS
Volume 25, Issue 43, Pages 7906-7910Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.3c03148
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In this paper, the synthesis of pi-conjugation-extended vinyl sulfoxonium ylides from vinyl sulfoxonium ylide and electron-deficient alkynes is reported. The new dienoate ylides are utilized in various transformations, including X-H (X = S, O) insertion, halogenation, carbene-mediated transformation, and radical-mediated reductions, to obtain a range of conjugated dienoates.
Herein, we report the synthesis of pi-conjugation-extended vinyl sulfoxonium ylides from vinyl sulfoxonium ylide and electron-deficient alkynes. The new dienoate ylides are used in various transformations, such as X-H (X = S, O) insertion, halogenation, carbene-mediated transformation, and radical-mediated reductions to obtain a variety of conjugated dienoates.
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