Journal
ORGANIC LETTERS
Volume 25, Issue 37, Pages 6897-6901Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.3c02627
Keywords
-
Categories
Ask authors/readers for more resources
This study describes a Cu-catalyzed regio- and enantioselective protoboration of 2,3-disubstituted 1,3-dienes. The protocol operates under mild conditions and is applicable to symmetrically and unsymmetrically substituted dienes, providing access to homoallylic boronates with consistently high yield, regioselectivity, and enantiomeric ratio. Preliminary investigations suggest a complex mechanism.
A Cu-catalyzed regio- and enantioselective protoboration of 2,3-disubstituted 1,3-dienes is described. The protocol operates under mild conditions and is applicable to symmetrically and unsymmetrically substituted dienes, providing access to homoallylic boronates in consistently high yield, regioselectivity, and enantiomeric ratio. Preliminary investigations point to a complex mechanism.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available