Efficient and tunable emission CsPbClxBr3-x quantum dot glass for overcoming the lack of cyan gap in WLED

Recently, the photoluminescence (PL) performance and sta-bility of cyan emission perovskite quantum dot (PQD) were found to be inferior to other color emitting PQDs, which greatly limits their practical applications. In this Letter, CsPbClxBr3-x PQD glass with excellent hydrothermal sta-bility is successfully synthesized by a high-temperature melting method. Results review that the vacancy defects in [PbBr6]4- octahedra can be effectively compensated by excessive halogen doping, resulting in an improvement in the photoluminescence quantum yield (PLQY) of PQDs from 24.73% to 65.62%. In addition, compared to white light emitting diode (WLED) synthesized with commercial fluo-rescent powders, the introduction of CsPbCl2Br1 PQD glass effectively fills the cyan gap. Moreover, the WLED displays the color-rendering index (CRI) of 87 at correlated color temperature (CCT) of 5257 K, and the color gamut area reaches 126% of the National Television System Committee (NTSC). This work provides an effective way for improving the PL performance of PQDs and brings CsPbClxBr3-x PQD glass significant prospect in the optoelectronic applications. (c) 2023 Optica Publishing Group

Automated summary

This study successfully synthesized CsPbClxBr3-x PQD glass with excellent stability and improved the PL performance of cyan emission PQDs through excessive halogen doping. The introduction of CsPbCl2Br1 PQD glass fills the cyan gap in white LEDs and achieves a high color rendering index and color gamut area.