Removal of tetracycline by NaOH-activated carbon produced from macadamia nut shells: Kinetic and equilibrium studies

A NaOH-activated carbon was prepared from macadamia nut shell using the impregnation ratio of 3:1 (NaOH:char) (wt:wt). The obtained material (AC(M)) was characterized by several techniques and methodologies such as, N-2 adsorption-desorption isotherms, SEM, FT-IR, Boehm titration, and pH(pzc) The results demonstrated that the AC(M) is composed mainly of micropores (78.2%), presenting BET surface area of 1524 m(2) g(-1). Through the SEM and FT-IR analysis it could be observed that significant changes occurred on the material surface after the activation procedure. According to Boehm titration, the AC(M) has on its surface a majority of basic groups which is in agreement with the obtained pH(pzc) value of 8.74. The AC(M) was applied for tetracycline (TC) removal in order to assess its potential as an adsorbent. Thus, adsorption studies were carried out and several kinetic and isotherm models were employed. The isotherm model which best fitted to experimental data was Temkin, while the best fitted kinetic model was Elovich. ACM showed maximum monolayer adsorption-capacity (Q(m)) of 455.33 mg g(-1). The intraparticle diffusion and film diffusion mechanisms were studied by the equations of Weber & Morris and Boyd, respectively. According to the results, the limiting step of the adsorption of TC onto AC(M) is influenced by intraparticle diffusion and by film diffusion. (C) 2014 Elsevier B.V. All rights reserved.