Glucose-ethanol-assisted synthesis of amorphous CoO@C core-shell composites for electrochemical capacitors electrode

Amorphous core-shell CoO@C and Mn3O4@C composites have been synthesized by documenting a simple glucose-ethanol-assisted approach and characterized by SEM, TEM, X-ray diffraction, energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. Electrochemical measurements are performed to examine the CoO@C composites, and the result shows that CoO@C structure has much higher capacitance, higher energy and power density and better cycling performance than that of C/CoO hybrids. This improvement can be attributed to the nature of core-shell structure, which promotes fast Faradaic charging and discharging reaction and also minimizes both the ionic and electronic transportation distances and therefore improves the resulting electrode kinetic performance. (C) 2014 Elsevier B.V. All rights reserved.