Flatband λ-Ti3O5 towards extraordinary solar steam generation

Solar steam interfacial evaporation represents a promising strategy for seawater desalination and wastewater purification owing to its environmentally friendly character(1-3). To improve the solar-to-steam generation, most previous efforts have focused on effectively harvesting solar energy over the full solar spectrum(4-7). However, the importance of tuning joint densities of states in enhancing solar absorption of photothermal materials is less emphasized. Here we propose a route to greatly elevate joint densities of states by introducing a flat-band electronic structure. Our study reveals that metallic lambda-Ti3O5 powders show a high solar absorptivity of 96.4% due to Ti-Ti dimer-induced flat bands around the Fermi level. By incorporating them into three-dimensional porous hydrogel-based evaporators with a conical cavity, an unprecedentedly high evaporation rate of roughly 6.09 kilograms per square metre per hour is achieved for 3.5 weight percent saline water under 1 sun of irradiation without salt precipitation. Fundamentally, the Ti-Ti dimers and U-shaped groove structure exposed on the lambda-Ti3O5 surface facilitate the dissociation of adsorbed water molecules and benefit the interfacial water evaporation in the form of small clusters. The present work highlights the crucial roles of Ti-Ti dimer-induced flat bands in enchaining solar absorption and peculiar U-shaped grooves in promoting water dissociation, offering insights into access to cost-effective solar-to-steam generation.

Automated summary

This study proposes a method to greatly enhance solar absorption by introducing a flat-band electronic structure. By incorporating metallic oxide λ-Ti3O5 particles into a three-dimensional porous hydrogel-based evaporator and utilizing a special structure, efficient solar-to-steam generation is achieved, providing a new solution for seawater desalination and wastewater treatment.