4.6 Article

Enhanced optical contrast of Ag-doped Ge-Sb-Se-Te phase change films

Journal

MATERIALS LETTERS
Volume 349, Issue -, Pages -

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ELSEVIER
DOI: 10.1016/j.matlet.2023.134736

Keywords

Optical materials and properties; Phase transformation; Raman; XPS; Thin films

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The PCM Ge2Sb2Se4Te1 film doped by Ag (AGSST) was prepared using the PLD method, and its crystal structure, chemical bonding, and film complex refractive index were studied. AGSST underwent a phase transition after annealing. The crystalline AGSST exhibited a significantly lower extinction coefficient in the communication C-band (1550 nm), with a high figure of merit (FOM) of 7.48, surpassing that of undoped GSST. This outcome provides potential chalcogenide PCMs for the development of programmable nonvolatile photonics.
The phase change material (PCM) Ge2Sb2Se4Te1 film doped by Ag (AGSST) was prepared by the pulsed laser deposition (PLD) method. The crystal structure, chemical bonding and film complex refractive index were investigated. The AGSST undergoes a phase transition through annealing. The extinction coefficient of crystalline (CR) AGSST has been significantly lowered for the communication C-band at 1550 nm, with a figure of merit (FOM) of 7.48, surpassing that of undoped GSST. This outcome delivers chalcogenide PCMs that are potentially in the development of programmable nonvolatile photonics.

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