Journal
MACROMOLECULES
Volume 56, Issue 15, Pages 6099-6104Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.3c00813
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In this study, a new method for synthesizing fully N-substituted polyureas was reported, which involved the catalyst-free ring-opening copolymerization of aziridines and isocyanates. The fully N-pendent functionality on polyureas was achieved for the first time, with the substitution exhibiting a non-symmetric pattern. Various N-alkyl aziridines were successfully used to form polyureas when combined with p-tosyl isocyanate, allowing for facile variation of the non-symmetric N-substitutions. The synthesized non-symmetric N-substituted polyureas possessed cyclic topologies, and the copolymerization was proposed to proceed via a zwitterionic mechanism. These findings have important implications for the development of novel functional materials based on N-substituted polyureas.
There is no access to directly synthesizing fully N-substituted polyureas, let alone customizing the N-substitution's sequence of polyureas. In this work,we reporta new class of fully N-substituted polyureas synthesisfrom the catalyst-free ring-opening copolymerization of aziridinesand isocyanates. Fully N-pendent functionality onpolyureas was directly achieved for the first time, and interestingly,the substitution was aligned in a nonsymmetric manner. With p-tosyl isocyanate (TSI) as the isocyanate comonomer, awide variety of N-alkyl aziridines were amenablein forming polyureas, whereas the N-substituentson aziridines open avenues to facile variation of the polyureas'nonsymmetric N-substitutions. We synthesized fivenonsymmetric N-substituted polyureas, and the obtainedpolymers had cyclic topologies. The copolymerization was proposedto proceed via a zwitterionic mechanism. We believe that our findingsprovide key implications for novel functional materials based on N-substituted polyureas.
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