Graphitizability of Polymer Thin Films: An In Situ TEM Study of Thickness Effects on Nanocrystalline Graphene/Glassy Carbon Formation

Polymer pyrolysis has emerged as a versatile method to synthesize graphenoid (graphene like) materials with varying thickness and properties. The morphology of the thin film, especially the thickness, greatly affects the graphitizability and the properties of the graphenoid material. Using in situ current annealing inside a transmission electron microscope (TEM), the thickness-dependent structural evolution of the polymer film with a special focus on thickness effects is followed. At high temperatures, thin samples form large graphene layers oriented parallel to the substrate, whereas in thick samples multi-walled cage-like structures are formed. Moleclar Dynamics (MD) simulations reveal a film thickness of 40 angstrom below which, the carbonized layers align parallel to the surface. For thicker samples, the orientation of the layers becomes increasingly misoriented starting from the surface to the center. This structural change can be attributed to the formation of bonded multi-layers from the initially unsaturated activated edges. The resulting cage-like structures are stable even during simulated annealing at temperatures as high as 3500 K. An atomistic understanding of the formation of these structures is presented. The results clearly indicate the critical effect of thickness on the graphitizability of polymers and provide a new understanding of the structural evolution during pyrolysis.

Automated summary

Polymer pyrolysis is a versatile method to synthesize graphenoid materials with varying thickness and properties. The thickness of the thin film greatly affects the graphitizability and properties of the material. In situ current annealing inside a TEM reveals that thin samples form large graphene layers parallel to the substrate, while thick samples form multi-walled cage-like structures. MD simulations show that carbonized layers align parallel to the surface for films with a thickness below 40 angstrom, and become increasingly misoriented for thicker samples.