4.6 Article

Probing the deep mantle wedge in an active subduction zone: Xenoliths from the Mercaderes Volcanic District, Southern Colombia

Journal

LITHOS
Volume 464, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.lithos.2023.107401

Keywords

Mantle wedge; Subduction zones; Garnet-bearing mantle peridotite; Garnet-bearing mantle pyroxenite; Metasomatism

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This study provides important petrologic information on the mantle wedge above an active subduction zone in Southern Colombia. The researchers analyzed a unique suite of rock samples and found evidence of hydration, metasomatism, and partial melting in the mantle wedge. They also observed variations in lithotypes, textures, and mineral abundance, indicating different interactions with melts and fluids. This study sheds light on the complex petrological processes occurring in the mantle wedge and contributes to our understanding of subduction zone dynamics.
In subduction zones, the mantle wedge is the domain where liquid phases released by the oceanic subducting plates cause mantle hydration, metasomatism, and partial melting, producting the arc crust. However, direct petrologic information on mantle wedges overlying active subduction zones remains scarce. Here we constrain key aspects of the petrological evolution of the supra-subduction mantle underneath the active volcanic district of Southern Colombia (Mercaderes) by studying a unique suite of peridotite and pyroxenite xenoliths hosted by andesites and lamprophyres. These garnet-bearing peridotite, websterite, clino- and orthopyroxenite xenoliths equilibrated between 2.5 and 4 GPa and 1100-1200 degrees C. The studied rocks display considerable heterogeneity in terms of lithotypes, textures, mineral abundance and extent of metasomatic overprint. Most samples display finegrained mylonitic textures overprinting coarse-grained peridotite and garnet pyroxenite precursors; the EBSD study of undeformed garnet websterite samples suggests crystallization from melts and/or melt-rock reaction processes. Modal enrichment in clinopyroxene as well as in the alkalis and LREE contents in some garnet peridotite implies interaction with alkaline basaltic melts, whereas enrichment in silica, Pb and Sr in the garnetbearing orthopyroxenites records interaction with metasomatic, slab-derived liquids. Some garnet clinopyroxenite xenoliths display marked positive Sr anomalies and minor Eu anomalies, indicating derivation of these rocks from Mg-rich, plagioclase-bearing (and garnet-absent) low-pressure cumulates. Their equilibration in the garnet field implies that after crystallization these clinopyroxenites were transported to deeper levels in the mantle, as the result of foundering into the mantle of the dense arc roots, as already documented in Mercaderes and elsewhere in the Andes. In conclusion, the Mercaderes xenoliths probe a heterogeneous and chemically active domain of the Colombian mantle wedge, where deep sinking lower crustal rocks, melt metasomatism by distinct venues of chemically different melts, and deformation predate fast exhumation by volatile-rich melts.

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