Journal
LITHOS
Volume 458, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.lithos.2023.107360
Keywords
Fe isotope; Mantle heterogeneity; Subduction zone; Backarc basin basalts; Island arc basalts
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The iron isotope heterogeneity of subduction-related primitive magmas is primarily caused by mantle melting processes. Additionally, the varied iron isotope compositions in subduction settings may reflect their heterogeneous sources, which may be related to plate subduction.
Iron isotope heterogeneity of subduction-related primitive magmas was traditionally thought to be predomi-nantly attributed to the addition of slab-derived components. However, the specific subducted material responsible for inducing Fe isotope heterogeneity in the subarc-backarc mantle remains poorly constrained. Here we report Fe isotopic compositions of a series of backarc basin basalts (BABBs) from the Woodlark Basin (an intra-arc rift basin), Vate Trough (a nascent rear-rift basin), and Lau Basin (a relatively mature basin) in the southwestern Pacific. Even though these BABBs have various geochemical compositions ranging from mid-ocean ridge basalts (MORB)-like to arc-like, which should be affected by various amounts of the slab-derived fluids and/or sediment melts, their delta 56Fe values (0.05-0.18%o) are within the range of global MORB (0.05-0.17%o). After correction for crystal fractionation, the primitive delta 56Fe values (delta 56Fe-prim) displayed no co-variation with indicators of subduction contributions (e.g., Ce/Pb, Nb/U, Ba/La, and Th/Yb) or source redox conditions caused by slab inputs (e.g., V/Yb, V/Ti), suggesting that the delta 56Fe-prim values of these BABBs are rarely affected by subduction metasomatism and the change in oxygen fugacity caused by subducted input. Therefore, we proposed that the MORB-like delta 56Fe values of the studied BABBs were primarily caused by mantle melting processes. Furthermore, we presented a compilation of available Fe isotopic data for BABBs and island arc basalts (IABs) and used these data to evaluate Fe isotope heterogeneity in subduction settings. In particular, compared with delta 56Fe-prim of MORB, the delta 56Fe-prim of BABBs from the Central Lau Spreading Centre in the Lau Basin and the IABs have lower values, whereas BABBs from the Rochambeau Ridges in the Lau Basin have higher delta 56Fe-prim values. By comprehensively considering the factors affecting the variation in Fe isotopic compositions in magmatic rocks in subduction zones (e.g., crystal fractionation, partial melting of the mantle, redox conditions, and subduction-related metasomatism), we proposed that the varied Fe isotopic compositions in subduction settings could reflect their heterogeneous sources, which may be related to plate subduction. Specifically, during plate subduction, a melt-depleted refractory forearc mantle peridotite (with low delta 56Fe values) could be dragged by subducted slab into subarc or backarc depths, resulting in light Fe isotopic enrichment in island arc magmas or BABBs; additionally, serpentinites (both in the slab and mantle wedge) can generate light Fe isotopic enrichment in island arc magmas. High delta 56Fe values in the BABB (e.g., from the Rochambeau Ridges in the Lau Basin) may result from the toroidal influx of nearby upwelling plume components or the assimilation of hydrothermally altered oceanic crust.
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