Journal
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
Volume -, Issue -, Pages -Publisher
SPRINGER
DOI: 10.1007/s10008-023-05620-9
Keywords
Chloride ion batteries; Magnesium anode; Mg2Sn alloy; Interfacial activity; Mechanical milling; Graphene
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Magnesium has potential as an anode material for chloride ion batteries due to its resources, multi-electron reaction feature, and high capacity. However, the passivation of magnesium and formation of insulating MgCl2 discharge product limits its reaction activity. This study introduces the Mg2Sn alloy as an anode material, showing enhanced interfacial activity and improved discharge capacity in the chloride ion battery. Furthermore, the incorporation of graphene nanoplatelets further increases the discharge capacity and improves the cycling performance of the magnesium anode.
Magnesium has been regarded as an intriguing anode material for chloride ion batteries (CIB) because of its abundant resources, multi-electron reaction feature, and high volumetric capacity. However, the passivation of magnesium in the electrolyte and formation of insulating MgCl2 discharge product lead to poor reaction activity of magnesium anode in CIBs. Herein, the Mg2Sn alloy prepared by mechanical alloying of magnesium and tin powders is first developed as the anode material with enhanced interfacial activity in the CIB using a metal chloride cathode. The cathode exhibits a significant increase in the discharge capacity from 82 to 175 mAh g(-1) when an Mg/carbon anode was replaced by the Mg2Sn alloy anode. The discharge capacity can be further increased to more than 200 mAh g(-1) when the graphene nanoplatelet is incorporated in the Mg2Sn alloy by mechanical milling, thus demonstrating the highly active alloy anode for chloride ion storage. This strategy also benefits the improvement in the cycling performance of the magnesium anode.
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