4.7 Article

Rhodaelectro-Catalyzed Decarboxylative Cross-Dehydrogenative Coupling of Indole-3-carboxylic Acids and Olefins via Weakly Coordinating Carboxyl Groups

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 88, Issue 21, Pages 15198-15208

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.3c01690

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In this study, a rhodaelectro-catalyzed C2-H selectively decarboxylative alkenylation of 3-carboxy-1H-indoles using electricity as the traceless terminal oxidant has been achieved. The weakly coordinating carboxyl group serves as the traceless directing groups.
A rhodaelectro-catalyzed C2-H selectively decarboxylative alkenylation of 3-carboxy-1H-indoles employing electricity as the traceless terminal oxidant has been accomplished. The weakly coordinating carboxyl group serves as the traceless directing groups. External oxidant-free in an undivided cell with constant current in aqueous solution ensures the decarboxylative C-H alkenylation to be viable and sustainable.

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