Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 88, Issue 19, Pages 14131-14139Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.3c01675
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An efficient methodology has been developed for the synthesis of 4-alkoxy- and 4-aryloxybenzo[d][1,2,3]triazines via an intramolecular heterocyclization of 1-azido-2-[isocyano(p-tosyl)methyl]benzenes under basic conditions. DFT calculations were performed to gain a better understanding of the mechanism behind this heterocyclization, which demonstrated good to excellent yields with a broad scope.
An efficient methodology to form 4-alkoxy- and 4-aryloxybenzo[d][1,2,3]triazines via an intramolecular heterocyclization of 1-azido-2-[isocyano(p-tosyl)methyl]benzenes under basic conditions has been developed. DFT calculations have been performed to further understand the mechanism of this heterocyclization, which occurs in good to excellent yields with a broad scope.
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