Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 88, Issue 21, Pages 15106-15117Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.3c01591
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A metal-free one-pot oxidative cross-dehydrogenation coupling reaction has been developed for the formation of C-N/C-C bonds at the C2,3-positions of indoles with azoles and quinoxalinones. The proposed method has several notable features, including metal-free catalysis, the use of N-H free indoles as substrates, ease of operation, mild reaction conditions, and compatibility with a wide range of substrates.
A metal-free one-pot oxidative cross-dehydrogenation coupling reaction for the formation of C-N/C-C bonds at the C2,3-positions of indoles with azoles and quinoxalinones has been developed. The proposed method has several notable features, including metal-free catalysis, the use of N-H free indoles as substrates, ease of operation, mild reaction conditions, and compatibility with a wide range of substrates.
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