4.7 Article

Preparation of ultrastable oil-in-water emulsion as a robust superwettable and sustainable concrete release agent

Journal

JOURNAL OF MOLECULAR LIQUIDS
Volume 390, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.molliq.2023.123043

Keywords

O/W release agent; Wettability; Emulsions; Concrete removal; Interface chemistry

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In this study, a facile method for the fabrication of a wax-free oil-in-water release agent was presented. By optimizing the physical parameters and chemical properties, the newly formulated release agent showed excellent results on iron mould surfaces during on-site trials, indicating its promising potential in the construction industry.
Release agents are compounds that are applied on the surface of moulds to create a thin film that acts as a barrier to prevent adhesion. Water-based release agents are especially preferred during the formulation due to their ecofriendly nature and less toxicity. In this work, we present a facile fabrication of a novel wax-free oil-in-water (O/W) emulsion-based release agent as a sustainable and efficient commercial product for the proficient removal of concrete from mould. The newly formulated O/W release agent was synergistically stabilized by the combination of Sorbitan monostearate (span-60) and Sodium dodecylbenzene sulfonate (SDBS) from 0.6% to 4.0% surfactant concentrations. The surfactant ratio (1:1) was optimized as best based on the hydrophilic-lipophilic balance (HLB). Firstly, physical parameters such as high/shear speed (12000 rpm), oil/water ratio (60:40), temperature (55 degrees C), and high/shear time (10 min) were optimized. Afterward, the performance and chemical properties of the O/W release agent were investigated by monitoring surface morphology, density, viscosity, contact angle, droplet size, and pH. The new O/W release agent achieved excellent results during on-site trials on iron mould surfaces indicating the promising potential in the construction industry.

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