Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 453, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jhazmat.2023.131403
Keywords
Blender; Microplastic; Nanoplastic; Raman imaging; Algorithm; SEM
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Microplastics and nanoplastics have been found in our daily lives, but there is still uncertainty about the extent of the problem, especially with regards to nanoplastics. Through testing a blender used in the kitchen, researchers discovered a significant amount of microplastics and nanoplastics being released from the plastic container. They advanced the characterisation of microplastics and nanoplastics using Raman imaging, which allowed for direct visualisation and increased sensitivity. By improving imaging resolution and using image reconstruction techniques, the researchers were able to effectively characterise nanoplastics and enhance the signal-to-noise ratio of microplastics.
Microplastics and nanoplastics have secretly entered our daily lives but the extent of the problem is still unclear, as the characterisation is still a challenge, particularly for nanoplastics. Herein we test a blender that we use in our kitchen to make juice and we find that a significant amount of microplastics and nanoplastics (similar to 0.36-0.78 x 109 within 30 s) are released from the plastic container. We advance the characterisation of microplastics and nanoplastics using Raman imaging to generate a scanning spectrum matrix, akin to a hyperspectral matrix, which contains 900 spectra (30 x 30). By mapping these hundreds of spectra as images, with help of algorithms, we can directly visualise the microplastics and nanoplastics with an increased sensitivity from statistical point of view. Raman imaging has a main disadvantage of the imaging resolution, originating from the diffraction of the laser spot, which is proposed to be improved by shrinking the scanning pixel size, zooming in the scanning area to capture details of nanoplastics. Using image re-construction towards deconvolution, the nanoplastics can be effective characterised and the bumpy image of microplastics stemming from the signal variation can be sub-sequently smoothened to further increase the signal-noise ratio. Overall, the advancements on Raman imaging can provide a suitable approach to characterise microplastics and nanoplastics released in our daily lives, for which we should be cautious.
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