Fumed-Si-Pr-PNS as a Photoluminescence sensor for the Detection of Hg2+ in Aqueous Media

Fumed silica was functionalized by piperazine followed by the reaction with 2- naphthalenesulfonyl chloride to prepare Fumed-Si-Pr-Piperazine-Naphthalenesulfonyl chloride (Fumed-Si-Pr-PNS), which was characterized to demonstrate the effective attachment on the surface of fumed silica. The optical sensing ability of Fumed-Si-Pr-PNS was studied via diverse metal ions in H2O solution by photoluminescence spectroscopy. The results showed that Fumed-Si-Pr-PNS detected selectively Hg2+ ions. The prepared sensor showed almost high absorption at different pH for Hg ion. After drawing various diagrams, The detection limits were calculated at about 12.45 x 10(-6) M for Hg2+.

Automated summary

In this study, fumed silica was functionalized by piperazine and 2-naphthalenesulfonyl chloride to prepare Fumed-Si-Pr-Piperazine-Naphthalenesulfonyl chloride (Fumed-Si-Pr-PNS), which showed effective attachment on the surface of fumed silica. The optical sensing ability of Fumed-Si-Pr-PNS was studied and it was found to selectively detect Hg2+ ions in water solution.