4.7 Article

Synthesis and luminescence modulation of pyrazine-based gold(III) pincer complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 93, Pages 16629-16632

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07523h

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Funding

  1. European Research Council
  2. ERC [338944-GOCAT]

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The first examples of pyrazine-based gold(III) pincer complexes are reported; their intense photoemissions can be modified by protonation, N-alkylation or metal ions, without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF).

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