Insight into the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans in hazardous waste incineration and incinerators: Formation process and reduction strategy

Incineration technology has been widely adopted to safely dispose of hazardous waste (HW). While the incin-eration process causes the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Due to its extreme toxicity, many scholars have been committed to determining the PCDD/F formation process and reducing emissions in incinerators. Previous studies ignored the impact of incineration and fluctuation of feeding materials on PCDD/F formation in hazardous waste incinerators (HWIs). In this study, differences in PCDD/F formation between HWIs and municipal solid waste incinerators (MSWIs) were pointed out. The incineration section in HWIs should be carefully considered. Laboratory experiments, conventional analysis and thermog-ravimetry experiments were conducted. An obvious disparity of PCDD/F formation between 12 kinds of HWs was found. Distillation residue was found with remarkably higher PCDD/F concentrations (11.57 ng/g). Except for the Cl content, aromatic rings and C-O bond organics were also found with high correlation coefficients with PCDD/F concentrations (>0.92). And PCDD/Fs were formed through a chlorination process and structure for-mation process. All of these are helpful to further understand the PCDD/F formation process during HW incineration, optimize the operation conditions in HWIs and reduce the emission pressure of PCDD/Fs in the future.

Automated summary

Differences in PCDD/F formation between hazardous waste incinerators (HWIs) and municipal solid waste incinerators (MSWIs) were identified. Distillation residue showed the highest PCDD/F concentrations, and aromatic rings and C-O bond organics were highly correlated with PCDD/F concentrations. PCDD/Fs were formed through chlorination and structure formation processes. These findings enhance understanding of PCDD/F formation during HW incineration, facilitate optimization of HWI operation conditions, and reduce future PCDD/F emissions.