Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 24, Pages 5077-5080Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00698h
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Funding
- Bowling Green State University
- BGSU Building Strength program
- NSF [0087210, 1337296]
- Ohio Board of Regents Grant [CAP-491]
- Youngstown State University
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Soluble copper-based M4L4 lantern-type metal-organic cages bearing internal amines were synthesized. The solution state integrity of the paramagnetic metal-organic cages was demonstrated using NMR, DLS, MS, and AFM spectroscopy. 1D supramolecular pillars of pre-formed cages or covalent host-guest complexes selectively formed upon treatment with 4,4'-bipyridine and acetic anhydride, respectively.
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