Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 943, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2023.117575
Keywords
Spinel-layered; Li1; 2Mn0; 6Ni0; Fluorine doping; Cathode; Li-ion batteries
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The conflicting roles of F doping on the electrochemical performance of layered-spinel Li1.2Mn0.75Ni0.25O2-zFz (z = 0, 0.05, 0.1) cathode materials are studied. F doping content affects the phase ratio and leads to different effects on the cathode. When z = 0.05, it improves cycle stability but reduces cathode capacity. However, increasing F doping to z = 0.1 results in the best cycle stability with high capacity retention.
Herein, the conflicting roles of F doping on the electrochemical performance of layered-spinel Li1.2Mn0.75Ni0.25O2-zFz (z = 0, 0.05, 0.1) cathode materials are studied. The compound consists of Li1.2Mn0.6Ni0.2O2 and LiMn1.5Ni0.5O4 with their phase ratio depending on F doping content. When z = 0.05, it favors the spinel phase formation, leading to increased first Coulombic efficiency and improved cycle stabil-ity. However, it reduces the cathode capacity to 250 mAh g-1 at C/10 (the capacity of the pristine is 280 mAhg-1). With F doping content increasing to z = 0.1, the cycle stability of the cathode is the best, with 96 % capacity retention after 200 cycles at C/2. The high level of F stabilizes the structure, prevents phase tran-sition, and retards voltage decay. The result demonstrates a promising strategy for the design of composite cathode materials by F doping.
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