Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 13, Pages 2714-2717Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09774b
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Funding
- University of South Florida
- National Science Foundation [DMR-1352065, CHE-1152362]
- XSEDE [TG-DMR090028]
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The introduction of the combination of open metal site (OMS) and pi-complexation into MOF has led to very high ethylene-ethane adsorption selectivity at 318 K, as illustrated in the context of MIL-101-Cr-SO3Ag. The interactions with ethylene from both OMS and pi-complexation in MIL-101-Cr-SO3Ag have been investigated by in situ IR spectroscopic studies and computational calculations, which suggest that pi-complexation contributes dominantly to the high ethylene-ethane adsorption selectivity.
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