Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 14, Pages 2855-2858Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09592h
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Funding
- Dutch National Research School Combination Catalysis (NRSC-C)
- European Research Council [NANOCAT-259064, ALPROS-290886]
- Netherlands Organization for Scientific Research (NWO)
- Royal Netherlands Academy of Arts and Sciences (KNAW)
- Ministry of Education, Culture and Science [024.001.035]
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Zinc porphyrin dimers and trimers, in which the porphyrins are connected via a ruthenium metal core, exhibit large third-order nonlinear optical absorption coefficients and refractive indices. These properties are a result of the presence of multiple porphyrins, which lead to an extension of the pi-conjugated system and the octupolar effect.
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