4.7 Article

The crystalline sponge method: MOF terminal ligand effects

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 56, Pages 11252-11255

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc03840e

Keywords

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Funding

  1. US National Institutes of Health [U19-AI109673, F32-GM108415]
  2. Division of Chemistry (CHE), National Science Foundation [NSF/CHE-1346572]
  3. Division of Materials Research (DMR), National Science Foundation [NSF/CHE-1346572]
  4. US DOE [DE-AC02-06CH11357]
  5. Direct For Mathematical & Physical Scien
  6. Division Of Chemistry [1346572] Funding Source: National Science Foundation

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Bromide and chloride analogs of the commonly used zinc iodide-based metal organic framework for the crystalline sponge method were synthesized and evaluated. Inclusion of (1R)-(-)- menthyl acetate into these MOFs was analysed using third-generation synchrotron radiation, and the effects and potential benefits of varying the MOF terminal ligand are discussed.

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