Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 84, Pages 15438-15441Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05713b
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Funding
- SERB, DST New Delhi [SR/FT/CS-92/2011]
- SEED Grant of IIT Mandi
- DST
- CSIR
- IIT Mandi
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A conceptually new dimethyl sulfoxide (DMSO) based oxidation process without the use of any activator has been demonstrated for the oxidation of active methylenes and benzhydrols. The developed protocol utilizes the electrophilic center of DMSO for oxidation, which was unexplored before. Mechanistic investigation has confirmed that the source of oxygen is DMSO.
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