Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 27, Pages 5852-5855Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10336j
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Funding
- National Science Foundation of China [21272162]
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The dirhodium(II) catalyst Rh-2(esp)(2) allows direct solvent-free allylic and benzylic oxidations by T-HYDRO with a remarkably low catalyst loading. This method is operationally simple and scalable at ambient temperature without the use of any additives. The high catalyst stability in these reactions may be attributed to a dirhodium(II, II) catalyst resting state, which is less prone to decomposition.
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