Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 655, Issue -, Pages 253-261Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2023.11.013
Keywords
Zwitterionic polymer brush; Hydration lubricity; Viscoelastic measurement; Confined thin film; Frictional property
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In this study, the lubrication mechanism of a hydrated MPC polymer brush was investigated. It was found that the mechanism depends on the shear gap, with two states exhibiting low coefficients of friction: one where the osmotic pressure supports the load and allows flexible deformation of the brush film, and the other where the brush film undergoes compression and transitions to a fully elastic state.
Hypothesis: A hydrated 2-methacryloyloxyethyl phosphorylcholine (MPC) polymer brush exhibits exceptional lubricity. This lubrication mechanism has traditionally been attributed to either the inherent fluidity of the brush or the water film that forms owing to its hydrophilic nature. Given previous findings that the frictional properties of the MPC polymer brush film show load dependence, we hypothesize that the lubrication mechanism can be elucidated by examining the shear gap (varies owing to the load) dependence of the brush's viscoelastic response. Experiments: MPC polymer brush films with different thicknesses were prepared. Their viscoelastic responses were evaluated across different shear gap widths, and the frictional properties were subsequently compared across states with distinct viscoelastic behaviors. Findings: The observed shear viscoelasticity demonstrated a clear gap dependence that correlated with frictional attributes. Our data suggests that the lubrication mechanism shifts based on the shear gap. Specifically, two states exhibited low coefficients of friction: one where the osmotic pressure supports the load while allowing flexible deformation of the brush film, and the other where the brush film undergoes compression and transitions to a fully elastic state.
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