Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 58, Pages 11705-11708Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04677g
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Funding
- MRSEC program of the National Science Foundation [DMR 1121053]
- Dow Chemical Company through the Dow Materials Institute at UCSB
- NSF Graduate Research Fellowship
- California NanoSystems Institute
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Here we report the use of 10-phenylphenothiazine (PTH) as an inexpensive, highly reducing metal-free photocatalyst for the reduction of carbon-halogen bonds via the trapping of carbon-centered radical intermediates with a mild hydrogen atom donor. Dehalogenations were carried out on various substrates with excellent yields at room temperature in the presence of air.
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