Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 96, Pages 17166-17169Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07598j
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Funding
- National Science Foundation [CHE-1362541]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1362541] Funding Source: National Science Foundation
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An efficient intramolecular transannulation reaction of pyridotriazoles using internal alkynes en route to various fused polycyclic indolizines has been developed. For the first time it is shown that in addition to the well-established Rh- or Cu-catalyzed carbene mechanism, the transannulation reaction could also follow a Lewis acid-mediated electrophilic pathway.
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