4.7 Article

A Mo-doped TiNb2O7 anode for lithium-ion batteries with high rate capability due to charge redistribution

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 48, Pages 9849-9852

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02221e

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Funding

  1. National Research Foundation of Korea (NRF) grant - Korean government (MEST) (GCRC-SOP) [NRF-2011-C1AAA001-0030538, 2013M1A8A1040703]
  2. National Research Foundation of Korea [2011-0030539, 21A20131711119, 2013M1A8A1040703, 2014M1A8A1049295] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Mo-doped TiNb2O7 (TNO) anode material has shown excellent electrochemical performance, especially at high C-rates. Doping TNO with Mo6+ resulted in charge redistribution, leading to the enhancement of electronic conductivity (caused by bandgap narrowing) and Li+ diffusivity in the lattice.

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