4.7 Article

Hydrophobic monofunctionalized cucurbit[7]uril undergoes self-inclusion complexation and forms vesicle-type assemblies

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 18, Pages 3762-3765

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00236b

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Funding

  1. National Natural Science Foundation of China [21472149]
  2. US National Science Foundation [CHE-1110911, CHE-1404911]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [1110911] Funding Source: National Science Foundation
  5. Direct For Mathematical & Physical Scien
  6. Division Of Chemistry [1404911] Funding Source: National Science Foundation

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Hydrophobic monofunctionalized cucurbit[7]uril derivatives (1 and 2) were synthesized by clicking CB[7]-azide with propargylated alkylamines. Compounds 1 and 2 form self-inclusion complexes that are transformed into vesicle-type assemblies by addition of guests (3-5) as confirmed by H-1 and DOSY NMR, SEM, TEM, and fluorescence spectroscopy.

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