Journal
JOURNAL OF CATALYSIS
Volume 427, Issue -, Pages -Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2023.08.011
Keywords
Palladium catalyst; Carbonylation; Cyclization; Nitroarene; 2-Pynones
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A palladium-catalyzed carbonylative synthesis of carboxamide substituted 2-pynones from methyl enynoates and nitroarenes has been developed. A wide range of carboxamide substituted 2-pynones were obtained in moderate to high yields with quite high functional group compatibility using nitroarenes as the nitrogen sources and Mo(CO)6 as both CO surrogate and reductant. Late-stage modifications of natural molecules were also achieved.
A palladium-catalyzed carbonylative synthesis of carboxamide substituted 2-pynones from methyl enynoates and nitroarenes has been developed. With nitroarenes as the nitrogen sources, and Mo(CO)6 as both CO surrogate and reductant, a wide range of carboxamide substituted 2-pynones were obtained in moderate to high yields with quite high functional group compatibility. Moreover, the late-stage modifications of natural molecules was also achieved.
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