Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 14, Pages 2995-2998Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10027a
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Funding
- French National Research Agency (ANR) [Carbiored ANR-12-BS07-0024-03]
- French State Program 'Investissements d'Avenir' (Grants LABEX DYNAMO) [ANR-11-LABX-0011]
- Direction Generale de l'Armement (DGA)
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A strategy is proposed for immobilization of homogeneous catalysts whereby a glassy carbon electrode is functionalized by electro-grafting of a ligand, terpyridine. The modified electrode can easily be metallated with cobalt and shows activity towards catalytic proton and CO2 reduction. The metal can be removed and the electrode re-metallated at will.
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