Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 37, Pages 7802-7804Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00723b
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Funding
- MEXT, Japan
- JST, Japan
- ACT-C, Japan
- Grants-in-Aid for Scientific Research [25105748] Funding Source: KAKEN
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The first synthesis of planar-chiral benzosiloloferrocenes was achieved by the intramolecular reaction of 2-(dimethylhydrosilyl)-arylferrocenes. The enantioselective cross dehydrogenative coupling of an sp(2) C-H bond of ferrocene with a Si-H bond proceeded efficiently with the use of a Rh-chiral diene catalyst.
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