Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 19, Pages 4069-4072Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10446c
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Funding
- National Basic Research Program of China [2015CB856600]
- NSFC [21422206, 21272206]
- Fundamental Research Funds for the Central Universities [2014QNA3008]
- Qianjiang Project [2013R10033]
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A nickel-catalyzed thiolation of unactivated C(sp(2))-H bonds with disulfides employing the PIP directing group was described. This process uses a catalytic nickel catalyst and no metallic oxidants or cocatalysts are required. The reaction tolerates various important functional groups and heteroarenes, providing an efficient synthetic pathway to access diverse diaryl sulfides.
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