4.7 Article

A Troger's base-derived microporous organic polymer: design and applications in CO2/H2 capture and hydrogenation of CO2 to formic acid

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 7, Pages 1271-1274

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08295h

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Funding

  1. National Natural Science Foundation of China [21125314, 21321063, 21402208]
  2. Chinese Academy of Sciences

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A Troger's base-derived microporous organic polymer (TB-MOP) was designed, which could adsorb CO2 and coordinate with a Ru(III) complex. The resultant TB-MOP-Ru showed good CO2 and H-2 adsorbing performances, and high efficiency for catalysing hydrogenation of CO2 to HCOOH with a turnover number up to 2254 at 40 degrees C.

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