Enhanced electrochemical performance of LiNiO2 cathode material by precursor preoxidation for lithium-ion batteries

In this study, the electrochemical performance of LiNiO2 is obviously improved via a method of precursor peroxidation with K2S2O8 in an alkaline medium. XRD, XPS and TEM show that NiOOH was formed on the preoxidized precursor surface. The optimal oxidation time of the precursor is 30 min (N30 precursor), XRD results show that the N30 LiNiO2 has an lowered Li+/Ni2+ cation-mixing. SEM and TEM results show that the surface of N30 LiNiO2 particles is denser and ordered, and the ordered lattice fringes formed two-dimen-sional pathways that facilitate the diffusion of Li+. Charge-discharge test results show that the initial dis-charge capacity of the original LiNiO2 is only 177.4 mAh g-1 at 1 C and the capacity retention rate of 100 cycles is 63.9 %. However, the above two data reach to 190.9 mAh g-1 and 88.6 % for N30 LiNiO2. In addition, the discharge capacity of N30 LiNiO2 at 5 C is similar to 150 mAh g-1, which is much higher than that of the original LiNiO2 (similar to 80 mAh g-1). CV and EIS results indicate that the cycling stability is improved and the charge transfer resistance is reduced. This study provides a better prospect for the commercial application of LiNiO2 materials. (c) 2023 Elsevier B.V. All rights reserved.

Automated summary

The electrochemical performance of LiNiO2 is significantly improved by preoxidation of the precursor with potassium peroxydisulfate in an alkaline medium. The optimized oxidation time is 30 minutes, resulting in denser and more ordered surface structure of LiNiO2 particles. The initial discharge capacity and capacity retention rate of N30 LiNiO2 are greatly enhanced compared to the original LiNiO2.