4.7 Article

Enhanced reversible conversion of Cu2S anodes for Na-ion batteries enabled by carbon nanotubes

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 953, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2023.170161

Keywords

Sodium-ion battery; Anode; Cu2S; Carbon nanotube

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Sodium-ion batteries with copper(I) sulfide anodes have gained attention for their high capacity and safety. In this study, Cu2S/CNT anodes were prepared, and the highly conductive CNTs acted as catalysts to promote the reversible reaction kinetics of Cu2S. The Cu2S/CNT anodes exhibited efficient and reversible conversion compared to pure Cu2S anodes, due to the superior electron conductivity and high surface area of CNTs, as well as their inhibition of sodium polysulfide dissolution. This research contributes to the design of conversion-type materials with reversible mechanisms.
Sodium-ion batteries (SIBs) with copper(I) sulfide (Cu2S) anodes has been gaining significant attention because of their relatively high capacity and inherent safety. The highly reversible conversion of Cu/Na2S in charging process to pristine Cu2S is essential for its electrochemical properties. Here, we have prepared Cu2S/carbon nanotube (CNT) anode for SIBs, in which highly-conductive CNTs are employed as a catalyst to promote the reversible reaction kinetics of Cu2S anode. By using a combination of electrochemical and ex -situ X-ray diffraction analysis, we demonstrate that Cu2S/CNT anodes can be converted efficiently and re-versibly in comparison with a pure Cu2S anode. CNTs have superior electron conductivity and high surface area, and are therefore used for balancing the poor electronic conductivity of Cu2S and discharged products, as well as physically inhibition of the dissolution of sodium polysulfide. Consequently, a partially reversible conversion reaction is enabled during the charging process. In this study, we are contributing to the design of conversion-type materials that feature reversible mechanisms, opening up new possibilities for materials design.(c) 2023 Elsevier B.V. All rights reserved.

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