4.7 Article

Construction of a supported Ru complex on bifunctional MOF-253 for photocatalytic CO2 reduction under visible light

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 13, Pages 2645-2648

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09797a

Keywords

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Funding

  1. NSFC [21273035]
  2. 973 Programs [2014CB239303]
  3. Specialized Research Fund for the Doctoral Program of Higher Education [20123514110002]
  4. Award Program for Minjiang Scholar Professorship

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A MOF-253 supported active Ru carbonyl complex (MOF-253-Ru(CO)(2)Cl-2) was constructed for photocatalytic CO2 reduction under visible light irradiation. Its performance can be further improved by immobilization as a photosensitizer. This study highlights the great potential of using MOFs as a solid ligand and platform for the assembly of a complicated catalytic system.

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