4.7 Article

Effect of surface defect states on Zn(1-x)CdxS for enhanced photocatalytic hydrogen evolution

Related references

Note: Only part of the references are listed.
Article Chemistry, Physical

Synergistic charge transfer on n-WO3/p-WS2/Au ternary heterojunction material for solar energy-driven sustainable H2 production

Taeseong Kim et al.

Summary: This study investigates the effects of changes in charge transport and photo-quantity on photocatalytic water splitting using a new ternary heterojunction n-WO3/p-WS2/Au. The results show that the ternary heterojunction particles exhibit improved photochemical properties and can generate more hydrogen compared to single particles. The loaded Au acts as an electron trapper, expanding the reduction reaction sites and enhancing hydrogen generation.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Review Chemistry, Multidisciplinary

Recent advances in thermocatalytic hydrogenation of carbon dioxide to light olefins and liquid fuels via modified Fischer-Tropsch pathway

Yongjun Jiang et al.

Summary: This review summarizes the thermocatalytic hydrogenation of CO2 to light olefins and liquid fuels via modified Fischer-Tropsch synthesis (FTs) pathway. It discusses catalyst design, reaction mechanism, catalyst component, and key factors affecting catalytic performance. By highlighting the advantages and challenges of the FTs route, it provides a comprehensive perspective for the development of novel catalysts in the future.

JOURNAL OF CO2 UTILIZATION (2023)

Article Chemistry, Physical

Synergy of oxygen vacancies and thermoelectric effect enhances uranium (VI) photoreduction

Pan He et al.

Summary: The conversion of soluble U(VI) to relatively immobilized U(IV) by photocatalytic techniques is the most effective method to prevent uranium contamination. In this study, a novel photocatalyst (TiO2_x/1T-MoS2) that combines photochemistry and thermoelectric physics is reported. The photocatalyst utilizes oxygen vacancies to improve the photogenerated carrier separation rate and generates a large thermoelectric potential difference through a temperature gradient in the liquid environment, achieving efficient capture of U(VI) species.

APPLIED CATALYSIS B-ENVIRONMENTAL (2023)

Article Chemistry, Physical

Bi-doped twin crystal Zn0.5Cd0.5S photocatalyst for highly efficient photocatalytic hydrogen production from water

Guangwu Yang et al.

Summary: Bi-doped twin crystal Zn0.5Cd0.5S (Bi/ZCS) was prepared for the first time via a hydrothermal method and exhibited improved photocatalytic hydrogen production performance. The Bi doping enhanced light absorption, promoted carrier separation and transport, leading to a significant increase in hydrogen evolution rate and apparent quantum efficiency. Moreover, Bi/ZCS photocatalyst showed superior performance in seawater, providing a low-cost and efficient solution for solar hydrogen production.

APPLIED SURFACE SCIENCE (2023)

Article Chemistry, Physical

Modular calcination strategy to construct defect-rich nitrogen-doped Nb2O5 for boosting photocatalytic oxidation of cyclohexane to cyclohexanone in solvent-free conditions

Kuan Wang et al.

Summary: A series of modified N-doped Nb2O5 catalysts were prepared by using a modular calcination strategy combining hydrogen, vacuum, air, and ammonia modules. Among these modified catalysts, HN-Nb2O5 showed the best photocatalytic performance for the photo-oxidation of cyclohexane. The outstanding performance can be attributed to the abundant chemical defects of oxygen vacancies and Nb4+, as well as the presence of NOx species, which enhanced light absorption and effective electron-hole separation.

APPLIED SURFACE SCIENCE (2023)

Article Engineering, Environmental

Boosting piezo-photocatalytic activity of BiVO4/BiFeO3 heterojunctions through built-in polarization field tailoring carrier transfer performances

Qinfang Jing et al.

Summary: The semiconductor n-p heterojunctions BiVO4/BiFeO3 (BVO/BFO) were designed to enhance piezo-photocatalytic processes and achieved ultra-high and stable catalytic performance. The degradation rate of Rhodamine B (RhB) solution reached 98%, which was 6.12 times higher than photocatalysis and 4.36 times higher than piezoelectric catalysis. The n-type BVO nanoparticles on the surface of p-type BFO enabled the formation of a built-in polarization field, resulting in improved carrier transport performances. The remarkable photo-piezoelectric properties of BVO/BFO heterojunctions provide valuable insights for efficient piezo-photocatalysis in environmental remediation.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Thermodynamics

Supercritical CO2 mixture Brayton cycle with floating critical points for concentrating solar power application: Concept and thermodynamic analysis

Nan Zheng et al.

Summary: A novel concept of supercritical Brayton cycle with floating critical points is proposed, which can dynamically adjust the circulating mixture composition to obtain the desired critical points at different ambient temperatures. The CO2-H2S mixture cycle shows the best performance with an improvement of 1.3%-7.4% in efficiency over the entire temperature range when considering composition tuning. Feasible schemes for the composition tuning subsystem are proposed and compared in terms of energy consumption.

ENERGY CONVERSION AND MANAGEMENT (2023)

Article Environmental Sciences

Decoration of ZnO surface with tiny sulfide-based nanoparticles for improve photocatalytic degradation efficiency

Govindhasamy Murugadoss et al.

Summary: Modifying the surface of wide band gap ZnO nanoparticles with narrow bandgap semiconductors is an effective approach to enhance its applications. In this study, metal sulfides (CdS, Ag2S, and Bi2S3) were used to decorate ZnO surface for photocatalytic application. The crystal structure, surface morphology, and optical properties of the modified ZnO were characterized. The results showed the presence of decorated metal sulfide nanoparticles on ZnO surface, which tunned the band gap of ZnO into the visible region. Among the three catalysts, Ag2S decorated ZnO exhibited the highest photodegradation efficiency and catalytic activity for the degradation of crystal violet dye under natural sunlight.

ENVIRONMENTAL RESEARCH (2023)

Review Chemistry, Physical

Blue and green hydrogen energy to meet European Union decarbonisation objectives. An overview of perspectives and the current state of affairs

Giovanni Lagioia et al.

Summary: This article is a narrative literature review on the production technologies and handling methods of blue and green hydrogen to meet the European Union decarbonisation objectives by 2030. The implementation of the European hydrogen use roadmap faces challenges due to technical and infrastructure barriers. While green hydrogen is not yet competitive compared to fossil fuel-based hydrogen production, blue hydrogen can pave the way for its future development. It is important to prioritize the adaptation and upgrading of hydrogen storage and deployment, as well as regulations for international trade.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2023)

Review Chemistry, Multidisciplinary

Unraveling Structure-Performance Relationships in Porphyrin-Sensitized TiO2 Photocatalysts

Belen Vaz et al.

Summary: Porphyrins have been widely used as photosensitizers in the field of photovoltaics and photocatalysis due to their ability to transfer energy from light-collecting areas to reaction centers, similar to natural photosynthesis. However, while solar cell development has led to continuous improvement in the molecular design of these pigments, these innovations have not been efficiently applied to dye-sensitized photocatalysis. This review aims to explore recent advances in the role of porphyrin structural motifs as sensitizers in TiO2-mediated catalysis, providing valuable insights for the development of more efficient photocatalysts.

NANOMATERIALS (2023)

Article Engineering, Environmental

In-situ upcycling of cadmium from wastewater into core-shell ZnS@Zn0.58Cd0.42S heterojunction photocatalyst for environmental purification and H2 evolution

Lei Bi et al.

Summary: Uncontrolled exploitation of heavy metals has led to environmental pollution and depletion of mineral resources. To address these issues, the researchers developed a strategy to efficiently retrieve and convert heavy metals from contaminated environments into high-value-added products. They achieved this by using microalgae-derived yolk-shell microspheres containing multicomponent nanocores as an adsorbent, magnetic carrier, and photocatalyst assembly platform. The resulting core-shell heterojunction photocatalysts showed higher photocatalytic activity for hydrogen generation and organic pollutant degradation compared to commercial photocatalysts.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Chemistry, Physical

Trace Cu plus -dominated band structure engineering in CuxIn0.25ZnSy for promoting photocatalytic H2 evolution

Kun Li et al.

Summary: As an attractive semiconductor photocatalyst, (CuInS2)x-(ZnS)y has been intensively studied in photo-catalysis, due to its unique layered structure and stability. In this study, a series of CuxIn0.25ZnSy photocatalysts with different trace Cu+-dominated ratios were synthesized. It was found that doping with Cu+ ions can increase the valence state of In and induce a distorted S structure, resulting in a decrease in the semiconductor bandgap. The optimized Cu0.04In0.25ZnSy photocatalyst with a bandgap of 2.16 eV showed the highest catalytic hydrogen evolution activity (191.4 lmol.h-1) when the doping amount of Cu+ ions was 0.04 atomic ratio to Zn. Rh loaded Cu0.04In0.25ZnSy showed the highest activity among common cocatalysts, with an apparent quantum efficiency of 49.11% at 420 nm and a rate of 1189.8 lmol center dot h-1. The internal mechanism of photogenerated carrier transfer between semiconductors and different cocatalysts was also analyzed by the band bending phenomenon.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Article Materials Science, Multidisciplinary

First principles study on electronic and optical properties of Cu2CoGeS4 for photovoltaic conversion and photocatalytic applications

J. El Hamdaoui et al.

Summary: This study investigates the structural, electrical, and optical characteristics of Stannite Cu2CoGeS4 (CCGS) using first-principle calculations. The band gap energy is determined using two different potentials, and the results show that CCGS is a potential absorber material for solar systems. The study also explores the optical parameters and simulates solar cells based on CCGS, demonstrating its potential as a good choice for solar cells and photocatalytic water splitting.

MATERIALS RESEARCH BULLETIN (2023)

Article Chemistry, Physical

Ni/Co-bimetallic organic framework-derived NiS/Co3S4/ZnCdS heterojunction for efficient photocatalytic hydrogen production

Ruting Huang et al.

Summary: A simple strategy for the synthesis of a sulfide/solid solution heterojunction NiS/Co3S4/ZnCdS is proposed using a Ni/Co-bimetallic organic framework as a template. The resulting heterostructure greatly reduces the recombination of electrons and holes and shows excellent photocatalytic activity with a high H2 rate of 98.6 mmol h-1 g-1 in the presence of Na2SO3-Na2S as a sacrificial agent. The improved photocatalytic ability is attributed to the synergy between ZnCdS and NiS/Co3S4, which inhibits the agglomeration of ZnCdS nanoparticles and exposes more active sites.

APPLIED SURFACE SCIENCE (2023)

Article Chemistry, Applied

S-scheme heterojunction of ZnCdS nanospheres and dibenzothiophene modified graphite carbon nitride for enhanced H2 production

Han Li et al.

Summary: S-scheme heterojunction is a promising approach to improve the light absorption and charge recombination issues in g-C3N4-based photocatalysts. In this study, a ZCS@DBTCN S-scheme heterojunction photocatalyst was synthesized, which exhibited superior photocatalytic H2 production activity. The enhanced performance was attributed to the synergistic effect of intramolecular electric field and S-scheme heterojunction that enhanced charge separation and transport.

CHINESE JOURNAL OF CATALYSIS (2023)

Article Chemistry, Physical

Construction double electric field of sulphur vacancies as medium ZnS/Bi2S3-PVDF self-supported recoverable piezoelectric film photocatalyst for enhanced photocatalytic performance

Meng Li et al.

Summary: Piezoelectric materials can establish polarization electric field to drive the separation of photogenerated carriers. The ZnS-VS/Bi2S3-PVDF photocatalyst containing S vacancies demonstrates a synergistic effect of double electric fields to inhibit carrier recombination and enhance hydrogen evolution rate. This research provides a new platform for photocatalytic reduction of hydrogen evolution and holds promise for clean energy production.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Physical

NiAl-LDH In-Situ Derived Ni2P and ZnCdS Nanoparticles Ingeniously Constructed S-Scheme Heterojunction for Photocatalytic Hydrogen Evolution

Youlin Wu et al.

Summary: Surface modification of photocatalytic materials is an effective way to enhance their semiconductor activity. By utilizing a simple surface modification strategy and constructing abundant active sites, the photocatalytic activity can be improved. The introduction of NiAl-LDH-P can enhance the utilization of Zn0.5Cd0.5S on solar energy and promote the transfer rate of photogenerated carriers. The construction of the Zn0.5Cd0.5S/NiAl-LDH-P S-scheme heterojunction can change the hydrogen evolution site and improve the activity and stability of hydrogen production.

CHEMCATCHEM (2022)

Article Engineering, Environmental

Synergistic effect of oxygen defect and doping engineering on S-scheme O-ZnIn2S4/TiO2-x, heterojunction for effective photocatalytic hydrogen production by water reduction coupled with oxidative dehydrogenation

Jiaqing Liu et al.

Summary: A well-designed S-scheme O-ZnIn2S4/TiO2-x heterojunction was fabricated to achieve efficient photocatalytic hydrogen production via water reduction coupled with organic oxidative dehydrogenation. The synergistic effect of oxygen defect and doping engineering led to improved charge transfer and separation efficiency at the interface, resulting in remarkable H-2 and benzaldehyde production rates. The coupled reaction system displayed superior H-2 evolution activity compared to sacrificial reagent systems, with both water and organic molecules providing protons for H-2 production.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

Dodecylamine coordinated tri-arm CdS nanorod wrapped in intermittent ZnS shell for greatly improved photocatalytic H2 evolution

Guotai Sun et al.

Summary: A new photocatalyst, tri-arm CdS/ZnS core-shell nanorod, shows significantly enhanced photocatalytic performance with improved quantum efficiency and hydrogen evolution rate. This enhancement is attributed to the win-win situation between the CdS/ZnS heterojunction and the H+ adsorption resulting from DDA molecules.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

In-situ construction of direct Z-scheme sea-urchin- like ZnS/SnO2 heterojunctions for boosted photocatalytic hydrogen production

Shaodong Sun et al.

Summary: This study reports the in-situ synthesis of sea-urchin-like ZnS/SnO2 Z-scheme heterojunctions, which exhibit excellent photocatalytic activity by promoting carrier separation and maintaining high reduction ability.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Synthesis of g-C3N4/WO3-carbon microsphere composites for photocatalytic hydrogen production

Meng Sun et al.

Summary: A g-C3N4/WO3-carbon microsphere composite-based photocatalyst was successfully prepared by a one-pot thermal synthesis method for sunlight driven water decomposition to produce hydrogen. The composite photocatalyst exhibited improved photocatalytic properties and stability compared to pure g-C3N4. Under visible light and sunlight irradiation, the hydrogen production efficiency of the photocatalytic water decomposition was significantly enhanced. The addition of carbon microspheres increased the specific surface area of the composite photocatalyst and facilitated the transfer of photogenerated electrons in g-C3N4 nanosheets.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Composition-dependent activity of ZnxCd1-xSe solid solution coupled with Ni2P nanosheets for visible-light-driven photocatalytic H2 generation

Lin Wei et al.

Summary: In this study, a novel series of ZnxCd1-xSe with tunable band structure were fabricated using a solvothermal method. By integrating 2D Ni2P nanosheets as a cocatalyst, the photocatalytic H-2 generation performance of ZnxCd1-xSe semiconductors was significantly boosted, leading to enhanced stability and hydrogen production rate. The improved photoactivity of the Ni2P/ZnSe photocatalysts was attributed to the effective separation and migration of photoinduced carriers, showing promise for future photocatalytic applications.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Chemistry, Physical

Controlled preparation of hollow Zn0.3Cd0.7S nanospheres modified by NiS1.97 nanosheets for superior photocatalytic hydrogen production

Lili Lu et al.

Summary: The development of durable and efficient photocatalysts for H2 evolution is crucial for advancing research on solar-chemical energy conversion. A novel photocatalytic system based on Zn0.3Cd0.7S/NiS1.97 nanocomposite was designed, showing excellent efficiency and stability in H2 production.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Chemistry, Multidisciplinary

Sulfur Vacancy and Ti3C2Tx Cocatalyst Synergistically Boosting Interfacial Charge Transfer in 2D/2D Ti3C2Tx/ZnIn2S4 Heterostructure for Enhanced Photocatalytic Hydrogen Evolution

Tongming Su et al.

Summary: An ultrathin 2D/2D Ti3C2Tx/ZnIn2S4 heterostructure was designed with larger contact area and strong electronic interaction to promote charge carrier transfer, leading to enhanced photocatalytic hydrogen evolution. The synergistic effect of sulfur vacancy and Ti3C2Tx cocatalyst greatly improves electron transfer and separation of photogenerated charge carriers, increasing the efficiency of photocatalytic hydrogen evolution.

ADVANCED SCIENCE (2022)

Article Chemistry, Physical

One-pot synthesis of Ru/Nb2O5@Nb2C ternary photocatalysts for water splitting by harnessing hydrothermal redox reactions

Wenkang Xu et al.

Summary: MXenes, 2D transition metal carbides/nitrides, have shown great potential in fabricating novel composites with interesting photo-/electrochemical properties. A one-pot hydrothermal synthesis method for MXene-based photocatalyst was successfully validated, utilizing the reducibility of Nb2CTx MXene. The chemical valance of the noble metal Ru/Pt obtained by this method was closer to the metal state, significantly reducing the charge transfer resistance and leading to efficient photocatalytic hydrogen production.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Article Chemistry, Physical

Constructing Defect-Mediated CdS/g-C3N4 by an In-situ interlocking strategy for Cocatalyst-free photocatalytic H2 production

Jing Wang et al.

Summary: The construction of heterojunction photocatalysts with well-defined interfaces is crucial for enhancing photocatalytic hydrogen production efficiency. In this study, an in-situ interlocking reaction was used to anchor litchi-like CdS onto the defects of g-C3N4, forming a unique and strongly coupling interface. This strategy effectively improves the separation and transfer kinetics of photogenerated charge carriers. The resulting CdS/g-C3N4 photocatalyst exhibits a remarkable 36-fold increase in hydrogen generation rate compared to pure CdS under visible light irradiation.

APPLIED SURFACE SCIENCE (2022)

Article Engineering, Environmental

Knack behind the high performance CdS/ZnS-NiS nanocomposites: Optimizing synergistic effect between cocatalyst and heterostructure for boosting hydrogen evolution

Dandan Ma et al.

Summary: Introducing a co-catalyst and constructing a heterostructure are two effective strategies in improving the photocatalytic H2 evolution performance of semiconductors. This study successfully fabricated a co-catalyst NiS decorated ZnS/CdS heterostructure for efficient photocatalytic H2 evolution from water splitting. The optimized heterostructure showed a high hydrogen evolution rate without the need for additional noble metal co-catalyst, demonstrating the synergistic effect between the heterostructure and co-catalyst. The one-pot fabrication process allowed for the formation of closely contacted interfaces and sufficient exposure of active reaction sites, leading to enhanced H2 evolution ability.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Assessment of hydrogen production methods via integrated MCDM approach under uncertainty

Sukran Seker et al.

Summary: This study evaluates the sustainability of various hydrogen production methods and proposes a new multi-criteria decision-making method. The results suggest that electrochemical method is the most efficient and appropriate for hydrogen production, especially in handling harmful chemicals.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Surface disorder engineering in ZnCdS for cocatalyst free visible light driven hydrogen production

Enna Ha et al.

Summary: This study reports on defect engineering of ZnCdS with surface disorder layer through a simple room temperature treatment, leading to the formation of rich S vacancies and Zn vacancies, which significantly improve photo charge carrier transfer and photocatalytic properties of ZnCdS for enhanced H-2 generation under visible light. The disordered ZnCdS exhibits a highest photocatalytic H-2 production rate of 33.6 mmol.g(-1).h(-1), surpassing pristine ZnCdS and Pt loaded ZnCdS.

NANO RESEARCH (2022)

Article Multidisciplinary Sciences

Superheating of grain boundaries within bulk colloidal crystals

Xiuming Xiao et al.

Summary: Understanding the dynamics and melting behavior of grain boundaries is crucial for controlling the mechanical properties of materials. Experimental results demonstrate that all grain boundaries can be superheated and melt via a nucleation mechanism.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Physical

Fabrication of Ni2P Cocatalyzed CdS Nanorods with a Well-Defined Heterointerface for Enhanced Photocatalytic H2 Evolution

Mengdie Cai et al.

Summary: In this study, a novel non-noble metal photocatalyst was developed with a core-shell structure and a fast and effective charge separation and transfer mechanism, leading to a significantly improved photocatalytic hydrogen evolution rate and excellent stability.

CATALYSTS (2022)

Article Chemistry, Multidisciplinary

Versatile Gold Telluride Iodide Monolayer as a Potential Photocatalyst for Water Splitting

Bingru Hai et al.

Summary: In this study, we investigated the structural, electronic, and optical properties of monolayer gold telluride iodide (AuTeI). We found that the exfoliation of monolayer AuTeI from the bulk phase is favorable, and it has a larger bandgap and suitable edge positions for water splitting. Additionally, the exciton binding energy suggests efficient electron-hole separation.

NANOMATERIALS (2022)

Article Energy & Fuels

Nanomaterials as highly efficient photocatalysts used for bioenergy and biohydrogen production from waste toward a sustainable environment

Pooja Sharma et al.

Summary: The worrisome rise in global waste generation caused by population growth, urbanization, and industrialization has led to an increased demand for sustainable bioenergy production. Nanomaterials offer a promising solution for maximizing biofuel production rates and improving energy efficiency. The development of renewable biofuels, such as bioethanol and biohydrogen, has the potential to replace non-renewable fossil fuels and mitigate environmental pollution. Therefore, utilizing nanotechnology in bioenergy production from waste biomass is crucial for achieving sustainability and meeting global energy demands.
Article Chemistry, Physical

Photocatalytic activity of CoFe2O4/g-C3N4 nanocomposite toward degradation of different organic pollutants and their inactivity toward hydrogen production: The role of the conduction band position

Mohammed Ismael et al.

Summary: In this study, CoFe2O4/g-C3N4 p-n heterojunction photocatalysts were prepared by a simple calcination method. The characterization results showed that the synthesized photocatalysts had morphological structure, optical, and electrochemical properties. The photocatalytic activity of CoFe2O4/g-C3N4 p-n heterojunction photocatalysts was evaluated, and the results demonstrated that they exhibited efficient degradation of organic pollutants under visible light irradiation. The dominant active oxygen species responsible for the photodegradation reaction were identified as hydroxyl radicals.

FLATCHEM (2022)

Article Chemistry, Physical

Nanoarchitectonics of core-shelled hollow CuPc/Zn0.5Cd0.5S photocatalyst for stable hydrogen evolution under visible-light irradiation

Qianlong Yang et al.

Summary: A new hollow core-shelled composite photocatalyst CuPc/Zn0.5Cd0.5S was studied, which exhibited significantly increased hydrogen production under visible light irradiation, as well as prolonged lifetime of photo-carriers and higher visible light utilization efficiency.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Physical

Anchoring highly-dispersed ZnCdS nanoparticles on NiCo Prussian blue Analogue-derived cubic-like NiCoP forms an S-scheme heterojunction for improved hydrogen evolution

Kai Wang et al.

Summary: This study presents a novel zinc cadmium sulfide/nickel cobalt phosphide heterojunction for highly efficient photocatalytic hydrogen generation. The zinc cadmium sulfide/nickel cobalt phosphide-3% composite exhibits the highest photocatalytic hydrogen generation performance in a lactic acid aqueous solution at 450 nm, and demonstrates excellent photostability. This research provides a new perspective for solar energy conversion.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Chemistry, Physical

Dual cocatalyst modified CdS achieving enhanced photocatalytic H2 generation and benzylamine oxidation performance

Binshu Sun et al.

Summary: This study demonstrates the synthesis of PdS/CdS/MoS2 composite, which exhibits enhanced photocatalytic performance in hydrogen production and benzylamine oxidation. The improved activity is mainly attributed to high charge separation efficiency and lowered activation barrier. Furthermore, the introduction of PdS enhances the photo-corrosion stability of CdS.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Physical

Mo-N Bonds Effect Between MoSx Coupling With CoN For Efficient Photocatalytic Hydrogen Production

Hai Liu et al.

Summary: The facet-engineered surface and interface design in the preparation of efficient photocatalysts has attracted much attention. In this study, 3D MoSx was prepared using Polyvinylpyrrolidone (PVP) as a morphological modifier. CoN was added as an electron acceptor to greatly improve the hydrogen evolution performance of MoSx. The results showed that MoSx@CoN exhibited high hydrogen production activity and stability, providing new insights for the preparation of highly efficient photocatalytic hydrogen evolution materials.

CHEMCATCHEM (2022)

Article Engineering, Environmental

Enhanced CO2 conversion on highly-strained and oxygen-deficient BiVO4 photocatalyst

Saeid Akrami et al.

Summary: This study successfully overcomes the limitations of bismuth vanadate (BiVO4) in photocatalytic CO2 conversion by introducing oxygen vacancies and lattice strain, leading to a low recombination rate, enhanced conduction band level, and narrowed bandgap. The oxygen-deficient and highly-strained BiVO4 exhibits a high photocatalytic CO2 conversion rate comparable to that of the P25 TiO2 photocatalyst. The enhancement of photocatalytic activity is attributed to the modification of the band structure, enhanced light absorbance, prolonged lifetime of excited electrons, and the utilization of oxygen vacancies as activation sites for CO2 photoreduction.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Efficient Photocatalytic Hydrogen Production over NiS-Modified Cadmium and Manganese Sulfide Solid Solutions

Ksenia O. Potapenko et al.

Summary: New photocatalysts based on Cd1-xMnxS sulfide solid solutions were synthesized and characterized in this study, with NiS co-catalysts significantly enhancing photocatalytic activity and offering high stability in different solution environments. The use of nickel sulfide as an alternative to precious metal deposition is economically attractive.

MATERIALS (2022)

Article Chemistry, Physical

Highly stable γ-NiOOH/ZnCdS photocatalyst for efficient hydrogen evolution

Qianlong Yang et al.

Summary: An efficient gamma-NiOOH/ZnCdS photocatalyst with high hydrogen evolution activity and stable visible-light-driven performance was prepared by in-situ hydrothermal method. The gamma-NiOOH nanosheets distribute on the ZnCdS nanosphere surface, accelerating holes transfer and improving catalysis activity and photo-stability.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Photocatalytic performance and mechanism of hydrogen evolution from water over ZnCdS/ Co@CoO in sacrificial agent-free system

Yangyang Zou et al.

Summary: This study prepared a ZnCdS/Co@CoO composite photocatalyst by a simple hydrothermal reduction method, and achieved a high hydrogen evolution rate from pure water. It was found that the S-scheme heterojunction formed between ZnCdS and Co@CoO, as well as the abundant S vacancy, were crucial for improving the photocatalytic performance. This research provides insights for the design and preparation of more efficient non-noble metal photocatalysts.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Fiber-like ZnO with highly dispersed Pt nanoparticles for enhanced photocatalytic CO2 reduction

Xiaohong Ma et al.

Summary: A heterogeneous photocatalyst composed of Pt nanoparticles deposited on ZnO nanofibers was successfully synthesized for efficient conversion of carbon dioxide into chemical fuels. The Pt/ZnO hetero-junction nanocomposites exhibited superior photocatalytic activity and achieved a high CO-production rate.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Chemistry, Physical

Boosting the photocatalytic performance via defect-dependent interfacial interactions from electrostatic adsorption to chemical bridging

Youzi Zhang et al.

Summary: Defect-induced interfacial interaction in the graphene oxide quantum dot/indium sulfide hybrid leads to improved stability and efficiency. The introduction of sulfur vacancies increases the interfacial electron exchange, turning the interfacial interaction from weak adsorption to strong chemical bridging.

NANO ENERGY (2022)

Article Chemistry, Physical

Boosting Hydrogen Evolution Performance of a CdS-Based Photocatalyst: In Situ Transition from Type I to Type II Heterojunction during Photocatalysis

Xiangyu Meng et al.

Summary: In this study, a new strategy for photocatalytic hydrogen production is proposed. The hybrid photocatalyst composed of Ni-Co Prussian blue analogue and CdS is transformed into a more active hybrid photocatalyst consisting of NiS and CdS during photo-catalysis in the sulfur sacrificial reagent. This strategy can enhance the photocatalytic hydrogen production performance of the catalyst, and the transition of the carrier transfer mechanism is supported by transient absorption spectroscopy.

ACS CATALYSIS (2022)

Article Energy & Fuels

Fabrication of NiFe-PBA-S/ZnCdS form S-scheme for improved photocatalytic hydrogen evolution

Kai Wang et al.

Summary: By using hydrothermal vulcanization method, NiFe-PBA was converted to NiFe-PBA-S while maintaining its original three-dimensional cubic structure. NiFe-PBA-S/ZnCdS was successfully synthesized and showed significantly higher hydrogen evolution rate. The unique three-dimensional structure of NiFe-PBA-S acted as an excellent growth site for ZnCdS nanoparticles and inhibited the recombination of electron-hole pairs with S-scheme heterojunction. This research expands upon the notion of designing efficient photocatalysts for hydrogen evolution.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2022)

Article Chemistry, Physical

The role of Al2O3 interlayer in the synthesis of ZnS/Al2O3/MoS2 core-shell nanowires

Edgars Butanovs et al.

Summary: In this study, a synthesis strategy for heterostructured ZnS/Al2O3/MoS2 core-shell nanowires is described, and the role of the Al2O3 interlayer during synthesis is explored. The Al2O3 interlayer preserves the smooth surface of the nanowires and protects the core material during the conversion of ZnO to ZnS and MoO3 to MoS2.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Physical

Gas bubbling exfoliation strategy towards 3D g-C3N4 hierarchical architecture for superior photocatalytic H2 evolution

Hamza Majeed Ansari et al.

Summary: In this study, ultra-thin 2D g-C3N4 nanosheets were successfully self-assembled into a large-scale 3D macroporous structure with the assistance of NH4Cl through a gas bubbling exfoliation strategy. The doping of N and Cl was achieved during synthesis. The resulting hierarchical structure exhibited remarkable improvement in photocatalytic water reduction reaction.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Physical

Self-assembly of Ag photosensitized SrTiO3 3D binary architectures for highly efficient visible light-driven dyeing wastewater splitting

Ton Nu Quynh Trang et al.

Summary: Recent research has shown that semiconductor/metal hybrid nanostructures-based photocatalysts can significantly enhance hydrogen evolution and dye degradation performance while exhibiting high stability.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Physical

Modulating valence band to enhance the catalytic activity of Co-Cr-B/NG for hydrolysis of sodium borohydride

Huashuan Li et al.

Summary: Amorphous Co-Cr-B/NG catalysts were synthesized via chemical reduction method. The valence band center was introduced as a descriptor to investigate the catalytic activity of the catalysts. The results showed that the valence band center of the Co-Cr-B/NG hybrids can be significantly altered by regulating the Cr content, enabling the modulation of the catalysts' electronic structure. The hydrogen release rate exhibited a volcano-shaped relationship with the valence band center.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Article Chemistry, Multidisciplinary

MOF Derived C/N Co-Doped ZnO Modified through Facile In Situ Coupling with NixPy toward Photocatalytic H2O2 Production and H2 Evolution Reaction

Asheli Ray et al.

Summary: A porous C/N co-doped ZnO nano-granular particles modified with NixPy cocatalyst have been developed as an efficient photocatalyst. This photocatalyst exhibits enhanced light absorption ability in the visible region and higher photocatalytic activity for the production of H2O2 and H-2 as sustainable energy sources.

ADVANCED MATERIALS INTERFACES (2022)

Article Multidisciplinary Sciences

Enabling full-scale grain boundary mitigation in polycrystalline perovskite solids

Lichen Zhao et al.

Summary: Researchers have successfully mitigated grain boundaries in perovskite solar cells at both nano and submicron scales, leading to improved device efficiency and stability under various stress conditions.

SCIENCE ADVANCES (2022)

Article Chemistry, Multidisciplinary

One-Step Room-Temperature Synthesis of Bimetallic Nanoscale Zero-Valent FeCo by Hydrazine Reduction: Effect of Metal Salts and Application in Contaminated Water Treatment

Asmaa A. Koryam et al.

Summary: The initial salt composition affects the formation of zero-valent FeCo nanoparticles, with nitrate salts resulting in smaller particles. FeCo demonstrates pseudo-first-order and pseudo-second-order removal of Cu2+ and RB5, respectively, showing higher selectivity towards Cu2+.

ACS OMEGA (2022)

Review Chemistry, Multidisciplinary

Recent advances and perspectives for solar-driven water splitting using particulate photocatalysts

Xiaoping Tao et al.

Summary: Photocatalytic water splitting is a promising technology that converts and stores solar energy to chemical energy through artificial photosynthesis, offering potential for optimizing the energy situation and mitigating global warming effects. Recent advancements have been made in the development of new light-absorption materials, insights and strategies for photogenerated charge separation, and studies towards surface catalytic reactions and mechanisms.

CHEMICAL SOCIETY REVIEWS (2022)

Article Chemistry, Applied

Energy funneling and charge separation in CdS modified with dual cocatalysts for enhanced H2 generation

Meiyu Zhang et al.

Summary: Anchoring molecular cocatalysts on semiconductors can enhance the charge separation efficiency required for efficient photocatalysis. The study reveals that the conjugated molecule 2-mercaptobenzimidazole (MBI) facilitates energy funneling between semiconductor nanorods, leading to improved photocatalytic performance.

CHINESE JOURNAL OF CATALYSIS (2022)

Article Green & Sustainable Science & Technology

Tunable Bandgap Engineering of ZnxCd1-xSe Solid Solution with Controlled Ratio via a Facile One-Pot Synthesis for Visible-Light Photocatalytic H2 Production

Lin Wei et al.

Summary: A facile solution approach is developed to prepare ZnxCd1-x Se solid solutions with tunable energy band structures. The optimal Zn0.5Cd0.5Se exhibits superior photocatalytic performance and stability. This work provides a straightforward strategy to synthesize metal selenide for diverse photocatalytic applications.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2022)

Article Chemistry, Multidisciplinary

Reduced Mo-doped NiCo2O4 with rich oxygen vacancies as an advanced electrode material in supercapacitors

Chengchao Wang et al.

Summary: Reduced Mo-doped NiCo2O4 prepared through a dual-defect strategy exhibits enhanced electrical conductivity and facilitated charge transfer. As an electrode material in supercapacitors, it shows higher specific capacity, rate capability, and cycling stability.

CHEMICAL COMMUNICATIONS (2022)

Article Engineering, Environmental

Precise carbon doping regulation of porous graphitic carbon nitride nanosheets enables elevated photocatalytic oxidation performance towards emerging organic pollutants

Xueyan Zhang et al.

Summary: In this study, carbon-rich g-C3N4 nanosheets were prepared using a homogeneous carbon atom-self doping strategy, resulting in improved photocatalytic oxidation performance for organic pollutants.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Applied

Integration of 2D layered CdS/WO3 S-scheme heterojunctions and metallic Ti3C2 MXene-based Ohmic junctions for effective photocatalytic H2 generation

Junxian Bai et al.

Summary: A 2D/2D/2D layered heterojunction photocatalyst with cascaded 2D coupling interfaces was designed and constructed, which effectively promoted spatially directional charge separation and transport between CdS and WO3 nanosheets, resulting in an increased visible-light hydrogen evolution rate.

CHINESE JOURNAL OF CATALYSIS (2022)

Article Chemistry, Applied

Step-scheme ZnO@ZnS hollow microspheres for improved photocatalytic H2 production performance

Jie Jiang et al.

Summary: Constructing a step-scheme heterojunction is an efficient way to optimize the performance of a photocatalytic system, and in this study, a ZnO@ZnS step-scheme photocatalyst was successfully prepared with superior performance and efficient charge carrier separation.

CHINESE JOURNAL OF CATALYSIS (2022)

Article Chemistry, Physical

Noble-metal-free Cd0.3Zn0.7S-Ni(OH)2 for high efficiency visible light photocatalytic hydrogen production

Bo Lv et al.

Summary: The study designed and synthesized a noble-metal-free Cd0.3Zn0.7S solid solution and engineered a heterojunction hybrid material with Ni(OH)(2) nanosheets, aiming to improve light utilization and inhibit electron-hole recombination for efficient photocatalytic hydrogen production.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Chemistry, Physical

Engineering highly active Cd1-xZnxS nanopopcorns via zinc blende/wurtzite phase junctions for enhanced photocatalytic H2 evolution without a co-catalyst

Xiaosheng Guo et al.

Summary: Rational structure design of semiconductor photocatalysts plays a significant role in enhancing their sunlight-driven hydrogen-evolution performance. In this study, Cd1-xZnxS nanopopcorns with zinc blende/wurtzite phase junctions were synthesized using excess thioacetamide (TAA), showing improved visible-light photocatalytic H-2 evolution activity and a high apparent quantum yield. The results indicate that the Cd1-xZnxS samples with excess TAA not only enhance light absorption and hydrophilicity, but also promote the separation and migration of photoinduced electron-hole pairs due to the presence of type-II ZB/WZ phase junctions.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Multidisciplinary Sciences

Highly active deficient ternary sulfide photoanode for photoelectrochemical water splitting

Haimei Wang et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

Bifunctional Hydrogen Production and Storage on 0D-1D Heterojunction of Cd0.5Zn0.5S@Halloysites

Sen Lin et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Article Chemistry, Multidisciplinary

Single Unit Cell Bismuth Tungstate Layers Realizing Robust Solar CO2 Reduction to Methanol

Liang Liang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Physical

Fluorine-Doped TiO2 Materials: Photocatalytic Activity vs Time-Resolved Photoluminescence

Maria Vittoria Dozzi et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2013)

Article Chemistry, Multidisciplinary

The roles of defect states in photoelectric and photocatalytic processes for ZnxCd1-xS

Jianying Shi et al.

ENERGY & ENVIRONMENTAL SCIENCE (2011)

Article Chemistry, Physical

Optical and electrical transport properties of spray deposited CdS1-xSex thin films

A. A. Yadav et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2010)

Article Chemistry, Physical

Synthesis of wurtzite ZnS nanowire bundles using a solvothermal technique

Lanlan Chai et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2007)

Article Chemistry, Multidisciplinary

Photocatalytic nanodiodes for visible-light photocatalysis

HG Kim et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)

Article Chemistry, Multidisciplinary

Mass production and high photocatalytic activity of ZnS nanoporous nanoparticles

JS Hu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)