Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 953, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2023.170158
Keywords
Minimized TiO nanocatalysts; S8 cathodes; Less sulfuration; deterioration; Long-cyclic durability; Li-sulfur batteries
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Using economical oxide catalysts in sulfur cathodes can effectively address kinetic issues in Li-sulfur batteries. To minimize the weight of catalysts in the cathode, titanium monoxide nanoclusters were proposed. These nanoclusters showed efficient kinetic-boosting properties and exhibited electrochemical stability without sulfuration or phase deteriorations during battery cycling. The S8 cathodes infused with lean TiO-involved carbon hosts showed high specific capacity and capacity retention ratio, indicating elevated viability and durability for practical usage.
Using economical oxide catalysts into sulfur (S8) cathodes proves an efficient way to address kinetic issues in Li-sulfur batteries (LSBs). However, these catalysts often occupy too much proportion in weight, thus attenuating the cathode gravimetric energy density. Also, they tend to be sulfurized/ deteriorated in electrode fabrication or battery cycling. To overcome above constraints, we herein propose to minimize the catalyst amount in S8 cathodes with titanium monoxide (TiO) nanoclusters. In such configured cathodes, there are only -1.47 % of TiO nano catalysts in weight; such oxides with rich (200) facet prove efficient kinetic-boosting properties on Li2Sn phase conversions. Notably, they exhibit prominent electrochemical stability over all cyclic periods, without evident sulfuration or phase deteriorations. The in-situ Raman monitoring toward LSBs reveals the liquid-to-solid polysulfide transitions can be well accelerated even under lean-catalyst conditions. As evaluated, the cathodes of S8 infused in lean TiO-involved carbon hosts (S8@L-TiO@CH) show a great specific capacity of 1331 mAh g-1 at 0.2 C, with a high capacity retention ratio of 78.5 % at the end of cycling. This work may guide a research trend to endow S8 cathodes with elevated viability/durability for practical usage.(c) 2023 Elsevier B.V. All rights reserved.
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