Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 955, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2023.170268
Keywords
FeOOH; NiFe-LDHs; Heterojunction; Energy density; Mechanism
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The same element heterojunction structure can effectively improve the energy density of the electrodes with its unique structural properties. In this study, a FeOOH/NiFe-LDHs heterojunction electrode achieved a specific capacitance of 4.34 F cm-2 at 2 mA cm-2 with a capacity retention of 95.67% after 6000 cycles. Additionally, a FeOOH@NiFe-LDHs//AC flexible supercapacitor device demonstrated a specific capacitance of 1.06 F cm-2 at 2 mA cm-2 and an impressive energy density of 0.47 mWh cm-2 at 1.78 mW cm-2, surpassing previous reports.
The same element heterojunction structure can effectively improve the energy density of the electrodes with its unique structural properties, but the specific mechanism of heterojunction action is not clear. Based on this, in this paper, the same element heterojunction electrode constructed with FeOOH on NiFe-LDHs can reach a specific capacitance of 4.34 F cm-2 at 2 mA cm-2. After 6000 cycles, its capacity is still maintained to 95.67% (30 mA cm-2). The FeOOH@NiFe-LDHs//AC flexible supercapacitor device was prepared to achieve a specific capacitance of 1.06 F cm-2 at 2 mA cm-2. More notably, an impressive energy density of 0.47 mWh cm-2 at 1.78 mW cm-2 was achieved, which is higher than previous reported. In addition, the capacitance remains 96.3% after 3000 cycles at 50 mA cm-2, and the electrode exhibited flexibility and outstanding bending stability. The high energy density of the electrodes in this study is attributed to the resulting Fermi energy level differences, which provide more carriers and increase the conductivity of the electrode ma-terial. This suggests that the heterojunction has obvious advantages for increasing the energy density of both flexible and non-flexible electrodes, and also provides new ideas for the application of supercapacitors in wearable electronic devices. (c) 2023 Elsevier B.V. All rights reserved.
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