Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 1, Pages 34-45Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06445c
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Funding
- Boehringer Ingelheim
- Bristol-Myers Squibb
- DuPont
- Eli Lilly
- Amgen
- AstraZeneca
- Roche
- A.P. Sloan Foundation
- S. T. Li Foundation
- Dreyfus Foundation
- University of California, Los Angeles
- Foote Family
- ACS Division of Organic Chemistry
- UCLA Graduate Division's DYF Program
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Heterocyclic arynes, or hetarynes, have been studied for over 100 years. However, challenges associated with observing these reactive species, as well as developing synthetically useful methods for their generation and trapping, have limited their use. This review provides a brief historical perspective on the field of hetarynes, in addition to a discussion of pyridyne and indolyne methodologies. Moreover, this review highlights the use of pyridynes, indolynes, and related strained intermediates in natural product synthesis.
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