Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5275-5278Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06344a
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Funding
- National Basic Research Program of China [2014CB910304]
- National Natural Science Foundation of China [21272260]
- Thousand Talents Program'' Young Investigator Award
- Shanghai Pujiang Investigator Award [12PJ1410700]
- State Key Laboratory of Bioorganic and Natural Products Chemistry
- Chinese Academy of Sciences
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We report a visible-light-induced reductive decarboxylative C(sp(3))-C(sp) bond coupling reaction to construct aryl, alkyl and silyl substituted alkynes at room temperature in organic solvents or neutral aqueous solutions. This chemoselective alkynylation was compatible with various functional groups and biomolecules, and did not affect the protein enzyme activity.
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