Journal
MICROPOROUS AND MESOPOROUS MATERIALS
Volume 234, Issue -, Pages 303-309Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2016.07.041
Keywords
SAPO-34; Copper; Solvent-free; Ion-exchange; NH3-SCR
Categories
Funding
- Assembly Foundation of The Industry and Information Ministry of the People's Republic of China [2012543]
- National Natural Science Foundation of China [51408309, 51578288]
- Science and Technology Support Program of Jiangsu Province [BE2014713]
- Natural Science Foundation of Jiangsu Province [BK20140777]
- Scientific Research Project of Environmental Protection Department of Jiangsu Province [2013003]
- Industry-Academia Cooperation Innovation Fund Projects of Jiangsu Province [BY2012025, BY2014004-10]
- Science and technology project of Nanjing [201306012]
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With the introduction of solvent-free method, copper-contained SAPO-34 zeolite was synthesized by mixing, grinding and heating the raw materials with Cu-TEPA added in the precursor. Compared to conventional method of hydrothermal synthesis along with ion-exchange, the direct synthesis with the absence of solvent has effectively reduced the waste production, increased the yield and accelerated the crystallization period as well. The so-prepared sample exhibited absolute symmetry of isolated Cu2+ by incorporating into the cativy of SAPO-34. The ion-exchange process produced some bulk CuO on zeolite surface, and it might affect the crystallinity of zeolite. The addition of copper led to changes in surface area, pore structure, redox performance and acid sites for SAPO-34. The exchanged sample show wide active temperature and excellent low temperature NOx conversion, but the activity and selectivity decreased significantly at a high temperature. The direct synthesized sample exhibited remarkable NOx conversion rate and high N-2 selectivity with a more efficient preparation, it also retained the excellent hydrothermal stability of chabazite structure. (C) 2016 Elsevier Inc. All rights reserved.
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