4.7 Article

A hybrid organic-inorganic molecular daisy chain

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 55, Pages 11126-11129

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02216a

Keywords

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Funding

  1. EPSRC(UK) [EP/K039547/1]
  2. European Commission (Marie Curie Intra-European Fellowship) [300402, 622659]
  3. Panamanian agency SENACYT-IFARHU
  4. Royal Society for a Wolfson Merit Award
  5. EPSRC [EP/K039547/1] Funding Source: UKRI
  6. Engineering and Physical Sciences Research Council [EP/K039547/1] Funding Source: researchfish

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A hybrid organic-inorganic molecular daisy chain has been synthesised in one pot reaction. The molecule contains two {Cr6Zn2} rings linked through an organic molecule that acts as both template and ligand. Magnetic and spectroscopic data reveal themagnetic complexity of the daisy chain, which can be casted to two magnetic isomers through comparison of experimental and simulated data for Cr(III) chains.

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