4.7 Article

High catalytic activity for water oxidation based on nanostructured nickel phosphide precursors

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 58, Pages 11626-11629

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02626a

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Funding

  1. NSFC [21271166, 21473170]
  2. Fundamental Research Funds for the Central Universities
  3. Program for New Century Excellent Talents in University (NCET)
  4. Thousand Young Talents Program

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For the first time, noble-metal-free nickel phosphide (Ni2P) was used as an excellent catalyst precursor for water oxidation catalysis. The lowest onset potential was observed at similar to 1.54 V (vs. RHE) and a Tafel slope of 60 mV dec(-1) was obtained in alkaline solution (pH = 13.6).

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