The effect of synthesis temperature on the particle size of nano-ZIF-8

The particle size and size distribution of Zeolitic Imidazole Framework-8 (ZIF-8) nanoparticles are influenced by the synthesis temperature during isothermal mixing reactions in methanol. As the synthesis temperature is increased from 15 degrees C to 60 degrees C, the average nanoparticle size decreased from 78 nm to 26 nm, with a simultaneous narrowing of the particle size distribution. Adsorption studies showed an increase in the external surface area of the nanoparticles from 220 m(2) g(-1) till 336 m(2) g(-1) as the particle size decreases from 78 nm till 26 nm. The increased external surface area of ZIF-8 nanoparticles (nZIF-8) led to a significantly higher catalytic activity when compared to the catalytic activity of commercially available ZIF-8 micro-particles in a Knoevenagel condensation test reaction. (C) 2015 Elsevier Inc. All rights reserved.