Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 27, Pages 5902-5905Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00839e
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Funding
- National Natural Science Foundation of China [21272028, 21202013]
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]
- Priority Academic Program Development of Jiangsu Higher Education
- Innovation & Entrepreneurship Talents'' Introduction Plan of Jiangsu Province
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A copper-catalyzed oxidative C(sp(3))-H/N-H coupling of sulfoximines with simple alkanes was developed. This protocol involved C(sp(3))-N bond formation via a radical pathway and tolerated a series of functional groups, such as chloro, methyl and aryl, on the phenyl rings. Apart from sulfoximines, amides, saccharin and aniline also worked well to give the corresponding N-alkylated products.
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